Assertion (A): Zinc, cadmium and mercury are not regarded as transition metals. Reason (R): Zinc, cadmium and mercury have completely filled d orbitals in their ground state but partly filled d orbitals in their common oxidation states.
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Zn, Cd and Hg of group 12 have a full d10 configuration both in the ground state and in their common oxidation states, so they are not regarded as transition metals. R wrongly says their common oxidation states have partly filled d orbitals, so A is true and R is false.
- A.
R is false, so it cannot explain A.
- B.
R is false: the d10 configuration is retained in their common oxidation states.
- D.
A is true: these metals are not regarded as transition metals.
NCERT: Class 12 Chemistry, Unit 4 (The d- and f-Block Elements), Electronic Configurations of the d-Block Elements