Assertion (A): Ethene is more acidic than ethyne. Reason (R): The carbon atoms in ethyne are sp hybridised and have 50% s character.
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The sp carbon of ethyne has 50% s character, the highest electronegativity among sp, sp2 and sp3 carbons, so the hydrogen attached to it is released as a proton most easily. Ethyne is therefore more acidic than ethene, so A is false while R is true.
- A.
A is false, so R cannot explain it.
- B.
A is false: ethyne is more acidic than ethene.
- C.
A is false and R is true, the reverse of this option.
NCERT: Class 11 Chemistry, Unit 9 (Hydrocarbons), Alkynes: Chemical properties, Acidic character of alkyne