A solution of ethylene glycol (C2H6O2) in water is 20% by mass. What is the mole fraction of ethylene glycol? (Molar masses: C2H6O2 = 62 g mol^-1, H2O = 18 g mol^-1)
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In 100 g of solution there are 20 g glycol (20/62 = 0.322 mol) and 80 g water (80/18 = 4.444 mol). Mole fraction of glycol = 0.322/(0.322 + 4.444) = 0.068.
- A.
0.25 is the mass ratio of glycol to water (20/80), not a mole fraction.
- B.
0.20 is the mass fraction, not the mole fraction.
- C.
0.932 is the mole fraction of water.
NCERT: Class 12 Chemistry, Chapter 1, 1.2